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Perception is your friend here my friend. Noticing people doing stuff is the whole point of it after all. And while sixth sense may (or may not) give a warning, Clairvoyance and/or Precognition could (presuming that the psi has either of course). As for finding the one odd charge? That depends on a whole host of factors (size of the charge, how much stuff is carried, how its carried, where the charge is put)

Also, if they do their pre-battle check, they should spot it.

However, by the rules, sixth sense didn't allow you to be caught unawares. This can mean they'd make a "dodge" roll to divest themselves of their deadly pack "just in time" to not get blown to hades and back.

Though it's really up to the GM.

Just watched the Richie Rich live film with that Home Alone kid.

You should get that device that tells you what it smells.

Could detect TNT and save your life.

and your wife